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The relative reaction rates and product branching ratios responded sensitively to the electronic property of the R group, providing key evidence to deriving a two-step reaction mechanism. The first ...
Factors Determining the Course and Mechanism of Grignard Reactions. XIV. Replacement of Halogen Atoms of Aromatic Halides with Hydrogen Atoms by the Action of Grignard Reagents and Cobaltous Chloride ...
Because of the high reactivity of Grignard reagents, a direct, highly enantioselective Grignard reaction with aldehydes has rarely been disclosed. In this report, Grignard reagents were introduced ...
Key Laboratory of Carcinogenesis and Translational Research (Ministry of Education), Department of Pharmacy, Peking University Cancer Hospital and Institute, Beijing, China Objectives: This study ...
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