A reaction mechanism is a sequence of elementary reactions that can explain how an overall chemical reaction proceeds. Gold redox catalysis has remained challenging owing to the high redox ...

Photocatalysis is a type of catalysis that results in the modification of the rate of a photoreaction - a chemical reaction that involves the absorption of light by one or more reacting species ...

So once the change has happened we cant go back again. If you crack an egg in a frying pan and heat it up, that is an irreversible reaction as you're never getting that raw egg back now.

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The bimodality of the oxime motif meant that by suitable choice of functionality the reactions could be directed to yield selectively products from either the N-centered radicals or from the ...