The utilization of covalent organic frameworks (COFs) holds great potential for achieving tailorable tuning of catalytic ...

The reaction is categorized as "C–C bond-forming aromatic electrophilic substitution (S N Ar)-type Birch reductive arylation via the mechanochemical anionic activation of unfunctionalized PAHs." ...

By constructing an aromatic hydrocarbon framework around an osmium ion, chemists have created a new class of organometallic compound. The in-plane metallo-annulenes are essentially carbon clusters ...

Furthermore, this strategy exhibits broad applicability, extending beyond azo synthesis to various aryl halides and nucleophilic aromatic compounds, offering an efficient approach for synthesizing ...

Researchers develop a one pot process to transform aromatic ketones to esters, offering advancements in pharmaceutical synthesis and materials science.

In undergraduate organic chemistry courses, nucleophilic substitution reactions are often carried out as an experiment. Reactions that occur at saturated carbons are chiefly categorized as S N 1 or S ...

The classic nucleophilic aromatic substitution (S N Ar) mechanism – described in all undergraduate textbooks as a two-step process – doesn’t apply to most molecules, US researchers have revealed. The ...

Nucleophilic aromatic substitution reactions with carbanions and nitranions in dimethyl sulfoxide solution Frederick G. Bordwell and David L. Hughes ...